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Solvation of Hg(CN)2, Hg(NO3)2 and Hg(CNS)2 by liquid ammonia; a raman spectroscopic study

✍ Scribed by Derek J. Gardiner; Ali H. Haji; Brian P. Straughan


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
588 KB
Volume
49
Category
Article
ISSN
0022-2860

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## Abstract 4‐Butoxynitrobenzene reacts with [Hg(O~2~CCF~3~)~2~] and LiCl to give [Hg(R)Cl] [R = C~6~H~3~NO~2~‐3, O__n__Bu‐6 (1)] which is symmetrized by Me~4~NCl to give [HgR~2~] (2), the crystal structure of which has been determined. The reaction of 2 with Me~4~N[AuCl~4~] affords Me~4~N[Au(R)Cl~