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Solvation of alcohols with different number of OH groups in mixed solvents H2O—1,4-dioxane and H2O—1,2-dimethoxyethane at 298.15 K

✍ Scribed by M. V. Kulikov; E. Yu. Trutneva

Publisher: Springer
Year: 1997
Tongue: English
Weight: 564 KB
Volume: 46
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf02502931

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📜 SIMILAR VOLUMES

Speeds of sound and isentropic compressi

Speeds of sound and isentropic compressibilities of {xH(CH2)νO(CH2)2O(CH2)2OH +(1 −x)H2O}, (ν= 1, 2, and 4) at the temperature 298.15 K

✍ A. Pal; Y.P. Singh 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 434 KB

The speeds of sound in {xH(CH2)n O(CH2)2O(CH2)2OH + (1-x)H2O} for n=1, 2, and 4 have been measured over the whole range of x at the temperature T=298.15 K. The molar isentropic compressibilities KS, m of these solutions were estimated from the products of the molar volume and the isentropic compress

Excess molar volumes of {x(C4H9)2O + (1−

Excess molar volumes of {x(C4H9)2O + (1−x)H(CH2)v(OCH2CH2)3OH} (v= 1, 2, and 4) at the temperature 298.15 K

✍ Amalendu Pal; Wazir Singh 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 390 KB

The excess molar volumes V E m of binary mixtures of {x(C4H9)2O + (1-x)H(CH2)n (OCH2CH2)3OH} for n=1, 2, and 4 have been measured as a function of mole fraction x using a continuous-dilution dilatometer at T=298.15 K. The V E m decreases in magnitude as the alkyl chain length of the alkoxyethanol in

Excess molar volumes and excess partial

Excess molar volumes and excess partial molar volumes of {xCH3O(CH2)2OH +(1 −x)H(CH2)νO(CH2)2O(CH2)2OH}, (ν= 1, 2, and 4) at the temperature 298.15 K

✍ A. Pal; W. Singh 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 375 KB

The excess molar volumes of {xCH3O(CH2)2OH+(1-x)H(CH2)nO(CH2)2O(CH2)2OH} for n = 1, 2, and 4 have been measured as a function of composition using a continuous-dilution dilatometer at the temperature T=298.15 K. The excess molar volumes are negative over the entire range of composition for the syste

Excess molar volumes and apparent molar

Excess molar volumes and apparent molar volumes of [xH(CH2)v{ O(CH2)2}3OH + (1 −x)H2O], (v= 1, 2, and 4), at the temperature 298.15 K

✍ Amalendu Pal; Yoginder P. Singh 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 394 KB

The excess molar volumes V E m of [xH(CH2)n {O(CH2)2}3OH+(1-x)H2O] for n=1, 2, and 4 have been measured using a continuous-dilution dilatometer over the whole mole-fraction range at the temperature 298.15 K. All three mixtures show negative V E m . The results were used to estimate the apparent mola

The speed of sound and isentropic functi

The speed of sound and isentropic functions of {xH(CH2)ν(OC2H4)2OH + (1−x)(C4H9)O} (ν = 1, 2, and 4) at the temperature 298.15 K

✍ A. Pal; Y.P. Singh 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 216 KB

The speeds of sound have been measured in {xH(CH2)n(OC2H4)2OH + (1x)(C4H9)2O} for n = 1, 2, and 4 as a function of mole fraction x at the temperature 298.15 K, using a sing-around technique, and at a frequency of 4 MHz. The excess molar volumes were taken from the literature and combined with the me

Speeds of sound and isentropic compressi

Speeds of sound and isentropic compressibilities of {xCH3O(CH2)2OH+(1−x)H(CH2)ν(OCH2CH2)2OH} (ν=1, 2, and 4) at the temperature 298.15 K

✍ A. Pal; W. Singh 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 209 KB

The speed of sound u has been obtained at a frequency of 4 MHz in 4xCH3O(CH2)2OH + (1 -x)H( CH2)n (OCH2CH2)2OH5 for n = 1, 2, and 4 over the whole range of x at T = 298.15 K and atmospheric pressure, using a NUSONIC velocimeter based on the sing-around technique. The excess molar volumes were taken