Solvation Effects on Geometry and Chemical Shifts. An Ab Initio/IGLO Reconciliation of Apparent Experimental Inconsistencies on H3B · NH3
✍ Scribed by Dipl.-Chem. Michael Bühl; Dr. Thomas Steinke; Prof. Dr. Paul von Ragué Schleyer; Prof. Dr. Roland Boese
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 274 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Details of the experimental setup are given elsewhere [lo, 121. A further modification of the high-Dressure cell was undertaken. The samhire win-
dow through which the radiation entered the cell was replaced with a 10 mm thick steel window into which a hole (9 mm deep, 8 mm diameter) was drilled. In this way sufficient radiation for accurate experiments could penetrate the cell. A Xe-Hg arc lamp was used to follow the reaction at 313 nm. the high light intensity of this lamp helped to increase the signalto-noise ratio of the kinetic traces. All experiments were performed at 17°C.
[12] a) R.