## Abstract __The solvation of tetramethylammonium chloride (Me~4~NCl) and tetra‐__n__‐butylammonium chloride (Bu~4~NCl) in water–acetonitrile mixtures was investigated by mass spectrometry of clusters isolated from the solution. As far as the positive ions are concerned, clusters composed of alkyl
Solvation Dynamics in Dipolar−Quadrupolar Mixtures: A Computer Simulation Study of Dipole Creation in Mixtures of Acetonitrile and Benzene
✍ Scribed by Ladanyi, Branka M.; Perng, Baw-Ching
- Book ID
- 127232414
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 267 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
A microscopic theory is described for the ion solvation dynamics in binary dipolar liquids. The theory is self-contained and properly includes inertial and non-Markovian effects which are extremely important in the fast initial phase of the relaxation. The theory also includes diffusional effects im
A series of molecular dynamics simulations have been performed to study the solvation shell of Na + and C1-ions in acetonitrile. Both structural and dynamic properties including reorientational and residence times, velocity autocorrelation functions, self-diffusion coefficients and spectral densitie