Solvation-controlled diastereofacial selectivity in alkylations of bicyclic lactam enolates
β Scribed by Durkin, Kathleen A.; Liotta, Dennis
- Book ID
- 127222346
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 301 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Ratios of the diastereomers 4 and 5 in the alkylation of the endocyclic enolates 3 with chirality at the B-position were highly dependent on the steric bulkiness of R1 and R2. It was clarified that, when the allylic strain considerations are acknowledged in 3, the diastereofacial selection is succes