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Solvation as a Factor in the Alkylation of Ambident Anions: The Importance of the Hydrogen Bonding Capacity of the Solvent

โœ Scribed by Kornblum, Nathan; Berrigan, Paul J.; Le Noble, William J.


Book ID
111985224
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
972 KB
Volume
85
Category
Article
ISSN
0002-7863

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Resorufin as a probe for the dynamics of
โœ Jongwan Yu; Mark Berg ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 476 KB

Resorufm is shown to be a good probe solute for the direct measurement of the rates of formation and breaking of solventsolute hydrogen bonds. In ethanol, a hydrogen-bond equilibration time of 40 ps is found for both the ground and excited states. Deuteration of the solvent has no effect on the equi