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Solvation and the Excited-State Tautomerization of 7-Azaindole and 1-Azacarbazole: Computer Simulations in Water and Alcohol Solvents

✍ Scribed by Mente, S.; Maroncelli, M.

Book ID
125902790
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
326 KB
Volume
102
Category
Article
ISSN
1089-5639

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πŸ“œ SIMILAR VOLUMES

Solvation and excited-state proton trans
Solvation and excited-state proton transfer of 7-azaindole in alcohols
✍ Y. Chen; F. Gai; J.W. Petrich πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 562 KB

Fluorescence lifetime measurements of purified 7-azaindole in methanol and butanol as a function of temperature are performed. The results indicate that in alcohols there exists a population of 'I-azaindole that is solvated in such a way that excitedstate tautomerixation is no longer a viable mode o

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Solvent-mediated proton transfer. The roles of solvent structure and dynamics on the excited-state tautomerization of 7-azaindole/alcohol complexes
✍ Dale McMorrow; Thijs J. Aartsma πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 496 KB

The time profile of the 7-azaindole tautomer emission in alcohol solvents consists of a superposition of two components with a different rise time. These observations are interpreted m terms of competitive hydrogen bonding leading to a ground-state equilibrium between different conformations of solu