✦ LIBER ✦

Solvation and approximation. Solvent effects on the bimolecular and intramolecular nucleophilic attack of carboxyl anion on phenyl esters

✍ Scribed by Bruice, Thomas C.; Turner, A.

Book ID: 126034764
Publisher: American Chemical Society
Year: 1970
Tongue: English
Weight: 778 KB
Volume: 92
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00714a033

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Intramolecular Carboxylate Attack on Est

Intramolecular Carboxylate Attack on Ester Groups. The Hydrolysis of Substituted Phenyl Acid Succinates and Phenyl Acid Glutarates 1

✍ Gaetjens, Erick; Morawetz, Herbert 📂 Article 📅 1960 🏛 American Chemical Society 🌐 English ⚖ 978 KB

Intramolecular Carboxylate Attack on Est

Intramolecular Carboxylate Attack on Ester Groups. II. The Effect of Diastereoisomerism in Polymers and their Low Molecular Weight Models 1

✍ Gaetjens, E.; Morawetz, H. 📂 Article 📅 1961 🏛 American Chemical Society 🌐 English ⚖ 667 KB

Determination of Dissociation Constants

Determination of Dissociation Constants of Ion Pairs from Kinetic Data of Bimolecular Nucleophilic Substitutions. I. The Importance of Solvation and Ion Pairing on the Nucleophilic Reactivity of the Halide Anions

✍ Weaver, William M.; Hutchison, J. Douglas. 📂 Article 📅 1964 🏛 American Chemical Society 🌐 English ⚖ 698 KB

Effects of anionic micelles on the intra

Effects of anionic micelles on the intramolecular general base-catalyzed hydrolysis of phenyl and methyl salicylates

✍ M.Niyaz Khan 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 814 KB

The effects of micelles of sodium dodecyl sulphate (SDS) on hydrolytic cleavage of phenyl salicylate (PS) have been studied at 30 and 37°C under [ NaOH] range 0.003-0.060 M. The total concentration of SDS, [SDS] =, was varied from 0.02 to 0.40 M. The observed pseudo first-order rate constants, kobsr

Resolution of racemic carboxylic acids v

Resolution of racemic carboxylic acids via the lipasecatalyzed irreversible transesterification using vinyl esters; Effects of alcohols as nucleophiles and organic solvents on enantioselectivity

✍ Toshifumi Miyazawa; Sota Kurita; Shinichi Ueji; Takashi Yamada; Shigeru Kuwata 📂 Article 📅 1992 🏛 Springer Netherlands 🌐 English ⚖ 303 KB

Ionic Hydrogen Bond Effects on the Acidi

Ionic Hydrogen Bond Effects on the Acidities, Basicities, Solvation, Solvent Bridging, and Self-Assembly of Carboxylic Groups

✍ Meot-Ner, Michael; Elmore, Donald E.; Scheiner, Steve 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 259 KB