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Solvated structure-retention relationships of peropyrne-type polycyclic aromatic hydrocarbons

✍ Scribed by J.C. Fetzer; W.R. Biggs

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
591 KB
Volume
322
Category
Article
ISSN
1873-3778

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✦ Synopsis

The peropyrene-type class of polycyclic aromatic hydrocarbons (PAHs) resulting from the zinc dust fusion of perinaphthone and benzanthrone, contains several members whose degree of planarity is highly dependent on the solvent in which the sample is dissolved. The reversed-phase behavior of these compounds is profoundly effected by the changes in planarity. The nature of, and changes in, the W-VIS spectra of these PAHs could be used to qualitatively predict which isomers would possess anomalous retention behavior.

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