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Solution thermodynamic studies. 5. A thermodynamic study of solvent effects on the relative stability of diastereoisomers. The trans-1,2-dibromo-4-tert-butylcyclohexane, trans-2,3-dibromodecalin, and 1-bromo-4-tert-butylcyclohexane systems

✍ Scribed by Ramos, J. J. Moura; Dumont, L.; Stien, M. L.; Reisse, J.

Book ID: 126114948
Publisher: American Chemical Society
Year: 1980
Tongue: English
Weight: 638 KB
Volume: 102
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00532a028

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A direct experimental and theoretical st

A direct experimental and theoretical study of solvent effects on the equilibrium between trans cis and trans trans 1,2-dibromo-4-t-butylcyclohexane

✍ Michael H. Abraham; Luigi E. Xodo; Raymond J. Abraham; Michael J. Cook 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 243 KB

The change in AGo for the equilibrium (1) = ( 2), R=t-Bu, has been measured for the gas phase and a range of solvents, thus providing a direct test of solvation theories.