## Abstract Glycine phosphite (NH~3~CH~2~COO.H~3~PO~3~), a potential ferroelectric material, was grown as single crystals from aqueous solutions by slow evaporation and slow cooling methods. Laboratory synthesized title compound was purified by recrystallization method and confirmed by Fourier tran
Solution growth of new ferroelectric glycine phosphite unidirectional single crystals at room temperature
✍ Scribed by R. Ezhil Vizhi; S. Kalainathan; G. Baghavan Narayana
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 158 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0232-1300
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✦ Synopsis
Abstract
Glycine phosphite [NH~3~CH~2~COOH~3~PO~3~], abbreviated as GPI is the second hydrogen bonded ferroelectric crystal combination of phosphorous acid and amino acid following βnine phosphite crystals abbreviated as BPI. Sankaranarayanan and Ramasamy‐Technique was adopted to prepare the ferroelectric glycine phosphite unidirectional single crystal. The growth orientation was imposed by the pre‐grown 〈010〉 seed. As water was the solvent, transparent, colourless crystal with cylindrical shaped ingot of sized 20mm‐diameter was grown. Powder X‐ray diffraction, HRXRD, FTIR, dielectric and mechanical studies were carried out. The results are discussed in detail. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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