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Solution equilibria in l-glutamic acid and l-serine + iron(III) systems

✍ Scribed by Predrag Djurdjevic´; Ratomir Jelic´

Book ID
110371621
Publisher
Springer
Year
1997
Tongue
English
Weight
244 KB
Volume
22
Category
Article
ISSN
0340-4285

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Complex formation in iron(III)-L-alanine solutions was studied by emf glass electrode and spectrophotometric measurements, in 0.5 mol dm-3 (Na)NO3 medium, at 25 ~ C. In the concentration range 0.5 ~< [Fe]o ~< 20.0, 5.0 ~< [Ala]0 ~< 1000.0 (mmoldm -3) and 1.0 ~< -log [H+-I ~< 3.5; { [Ala]/[Fe] = 10:1

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## Abstract The binding process between sodium poly(L‐glutamate) and __trans__‐2,2′,2″,2‴‐tetrapyridyl‐Fe(III) complex ions in aqueous solution at pH around 7 has been studied by means of equilibrium dialysis and optical measurements. The binding isotherm indicates the occurrence of a cooperative p

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