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Solution EPR spectra of reactive 1,5- and 1,6-biradicals

✍ Scribed by Forbes, Malcolm D. E.


Book ID
118119803
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
421 KB
Volume
115
Category
Article
ISSN
0002-7863

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Photolyses of 1-alkoxy-9-diazoanthrones 12 in benzene induce abstraction of hydrogen from the side chain, followed by cyclization (---) 15 --~ 16) or disproportionation (--~ 17 + 18) of the intervening biradicals 20. In alcohols, reduction of triplet anthronylidenes (314 ~ 21 ~ 22) competes with the