Intramolecular reactivity of 1-alkoxyant
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Frank Gotzhein; Wolfgang Kirmse
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Article
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1998
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Elsevier Science
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French
β 195 KB
Photolyses of 1-alkoxy-9-diazoanthrones 12 in benzene induce abstraction of hydrogen from the side chain, followed by cyclization (---) 15 --~ 16) or disproportionation (--~ 17 + 18) of the intervening biradicals 20. In alcohols, reduction of triplet anthronylidenes (314 ~ 21 ~ 22) competes with the