✦ LIBER ✦

Solution behaviour and redistribution reactions of tetraorganodistannoxane dimers

✍ Scribed by Vimal K. Jain; V. B. Mokal; P. Sandor

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 437 KB
Volume: 30
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260301203

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✦ Synopsis

Abstract

The solution behaviour and redistribution reactions of tetraorganodistannoxane dimers were investigated by ^19^F and ^119^Sn NMR spectroscopy. The variable‐temperature NMR data suggest that both the ‘ladder’ and ‘staircase’ structures exist in solution. Redistribution between two different tetrabutylstannoxanes is rapid on the NMR time scale. The ^119^Sn 2D EXSY NMR data for [Bu~2~Sn(F)OSnBu~2~(Cl)]~2~ indicate that there is no exchange between exo‐ and endocyclic tin centres.

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