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Solution and Solid State Studies on the Interactions of Protonated Cytosine Salts. IV. Asymmetric Interbase Hydrogen Bonding and Interpyrimidine Base Stacking in Triply Hydrogen-Bonded Cytosine Complexes. Crystal and Molecular Structure of Bis[1-Methylcytosine, 1-Methylcytosinium] Hexafluorosilicate Dihydrate

✍ Scribed by Thomas J. Kistenmacher; Miriam Rossi; Chian C. Chiang; John P. Caradonna; Luigi G. Marzilli

Publisher: Elsevier Science
Year: 1980
Weight: 959 KB
Volume: 17
Category: Article
ISSN: 0378-4487
DOI: 10.1016/0378-4487(80)80041-0

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The structural properties of the salts protonated 1-methylcytosine perchlorate and protonated l-benzylcytosine nitrate are reported. In each of the salts, it has been definitively established that N(3) of the cytosine ring is the site of protonation. Cation-anion hydrogen-bonding interactions of the