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Solution- and solid-state structure and dynamics of thiophosphonamide anions: electronic tuning of rotational barriers

โœ Scribed by Denmark, Scott E.; Swiss, Kevin A.; Wilson, Scott R.


Book ID
127023323
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
861 KB
Volume
115
Category
Article
ISSN
0002-7863

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Rotational barriers for P(V)-N bonds; th
โœ R. Keat; K.W. Muir; D.G. Thompson ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 159 KB

The measurement of rotational barriers for P(III)-N bonds by n.m.r. methods is now commonplace, 1 but such barriers involving P(V)-N bonds at four co-ordinated phosphorus are not generally accessible by this technique 2 and none has been reported for a dimethylamino-group. Even with relatively bulk