Solute?solvent and solvent?solvent interactions in binary solvent mixtures. Part 1. A comparison of several preferential solvation models for describing E T(30) polarity of bipolar hydrogen bond acceptor-cosolvent mixtures

Characterization of solvent mixtures. Pa

Characterization of solvent mixtures. Part 8 — preferential solvation of chemical probes in binary solvent systems of a polar aprotic hydrogen-bond acceptor solvent with acetonitrile or nitromethane. Solvent effects on aromatic nucleophilic substitution reactions

✍ P. M. E. Mancini; A. Terenzani; C. Adam; A. Pérez; L. R. Vottero 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 2 views

The use of chemical probes for the characterization of chemical properties was explored for completely non-aqueous aprotic binary solvent mixtures. The Dimroth-Reichardt E T (30) betaine dye, 4-nitrophenol, 4nitroanisole, 4-nitroaniline and N,N-diethyl-4-nitroaniline were used to study preferential