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Solute-solvent interactions. VI. Specific interactions of tetraphenylarsonium, tetraphenylphosphonium, and tetraphenylborate ions with water and other solvents

✍ Scribed by Coetzee, J. F.; Sharpe, W. R.

Book ID
118140882
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
789 KB
Volume
75
Category
Article
ISSN
0022-3654

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## Abstract Absorption spectra of the superoxide ion have been studied in dimethylformamide (DMF) and acetonitrile (AN). It was found that the superoxide ion existed in equilibrium with an ion pair in AN (__K__~eq~ = 20__M__^βˆ’1^, Bu~4~N^+^ is the cation) and as β€œfree” (solvated) ion in DMF. The add