Solute cavity radii in solution and polarizabilities in excited electronic states from solvatochromic data
β Scribed by Raul G.E. Morales; Gabriel Traverso
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 405 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0167-7322
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Using 25 ns half width pulses of a frequencyquadrupled Nd laser at 165 nm Tb3' perchlorate in D20 solution, or in b&ate glass, was excited to hip+ electronic s!ates and the fluorescence on transition from the upper 5 D3 and lower 'D+ excited states IO various sub-levels of the lowest 'F state were m
## Abstract During UV.βirradiation of aliphatic carboxylic acids and esters in aqueous and nonaqueous solutions various alkyl and acyl type radicals derived from parent compounds and solvents have been observed by ESR.βspectroscopy. The structures of the radicals point to Ξ±βcleavage, Ξ²βdehalogenati