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Soluble Polyimides from a New Dianhydride: 5′-tert-Butyl-m-terphenyl-3,4,3″,4″-tetracarboxylic Acid Dianhydride

✍ Scribed by Carolina García; Angel E. Lozano; José G. de la Campa; Javier de Abajo

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
109 KB
Volume
24
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

A novel tert‐butyl‐containing dianhydride was prepared from readily available reagents. It was reacted with various aromatic diamines to prepare a set of polyimides containing tert‐butyl pendent groups. The resulting polyimides exhibit high molecular weights (high inherent viscosity), and a combination of desirable properties, such as good solubility in aprotic amide solvents and cresols, high glass transition temperatures (up to 320 °C), high thermal resistance, film‐forming capability and good mechanical properties.

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