Soluble conductive polypyrrole synthesized by in situ doping with β-naphthalene sulphonic acid

✍ Scribed by Youqing Shen; Meixiang Wan

• Publisher: John Wiley and Sons
• Year: 1997
• Tongue: English
• Weight: 272 KB
• Volume: 35
• Category: Article
• ISSN: 0887-624X
• DOI: 10.1002/(sici)1099-0518(199712)35:17<3689::aid-pola8>3.0.co;2-n

✦ Synopsis

Soluble polypyrrole (PPy) with high conductivity (27 S/cm) has been prepared by chemical polymerization of pyrrol monomer in the presence of b-naphthalene sulphonic acid (NSA) as a dopant. The solubility of the resulting conducting polymer of PPy-NSA in m-cresol increases with increasing the concentration of NSA in the polymerization media, and the highest solubility of PPy-NSA in m-cresol is about 1.2 g/100 mL. The room-temperature conductivity of PPy-NSA significantly increases with the concentration of NSA when the concentration of NSA is less than 0.1 mol/L, while it slightly decreases with increasing the concentration of NSA after the concentration of NSA is higher than 0.1 mol/L. UV-VIS spectra and ESR measurements demonstrate that both polaron and bipolaron are present as a charge carrier. The resulting PPy-NSA exhibits unusual fibrillar morphology with a diameter of about 0.5 mm, which is quite different from the granular morphology of PPy doped with dodecyl benzene sulfonic acid (DBSA) and HCl. Moreover, the polymerization conditions greatly influence the morphology of the obtained PPy-NSA.