𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solubilization of polyaniline in water by interpolymer complexation

✍ Scribed by Yun-Hsin Liao; Kalle Levon; Jukka Laakso; Jan-Erik Österholm

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
227 KB
Volume
16
Category
Article
ISSN
1022-1336

No coin nor oath required. For personal study only.

✦ Synopsis

Water solubility of electro-active polymers in their doped state may provide a possibility for environmentally feasible manufacturing processes. Because previous results in this direction require expensive modifications or impractical template polymerization methods, we created a simple method of mixing components with a large molecular weight difference. The polymer which acts as an acidic dopant and provides water solubility, has to have the higher molecular weight. The formed complex resembles a block copolymer but in this case the polyaniline block is attached to the sulfonated polystyrene chain by strong physical interactions instead of chemical end-to-end linkage.

📜 SIMILAR VOLUMES

Water-soluble polypyrroles by matrix pol
Water-soluble polypyrroles by matrix polymerization: Interpolymer complexes
✍ A. Sezai̊ Saraç; Gürsel Sönmez; Belkis Ustamehmetoǧlu; Mamed I. Mustafaev 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 228 KB

A new class of water-soluble polypyrroles (PPy) has been developed. This was accomplished by oxidative matrix polymerization of pyrrole (Py) monomer with Ce(IV) in the presence of poly(acrylic acid) (PAA), poly(vinyl pyrrolidone) (PVP), and copolymers (CP) of vinyl pyrrolidone(VP) with acrylic acid

Facile synthesis of processable conducti
Facile synthesis of processable conductive water solubilized polyaniline
✍ Madathi Rethi; Surendra Ponrathnam; Chelanattu Raman Rajan 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB 👁 2 views

Conductive polyaniline, polyemeraldine green, was synthesized in a water soluble form by an in situ method, using surfactants with strong acid functionalities as protonating agents. The clear green solution of conducting polyaniline, polyemeraldine green, can be diluted to any extent and stored. Thi

Surface Complexation of Calcite by Carbo
Surface Complexation of Calcite by Carboxylates in Water
✍ C. Geffroy; A. Foissy; J. Persello; B. Cabane 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 120 KB

Small molecules that have two carboxylic functions can adsorb from water onto calcite. The adsorption site is a ؊Ca ؉ site. The mechanism of adsorption is a complexation of the ؊Ca ؉ site by the two carboxylates, similar to the solution complexation of Ca ؉؉ ions. The complex has a ring structure wh