Solubility of Iodine in 1,2- and 1,1-Dichloroethanes, cis- and trans-Dichloroethylenes and Perfluoro-n-heptane
β Scribed by Benesi, H. A.; Hildebrand, J. H.
- Book ID
- 126821659
- Publisher
- American Chemical Society
- Year
- 1948
- Tongue
- English
- Weight
- 482 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0002-7863
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The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22Β°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma
Cis and trans 1,2dichloroethylene react with LiPPha [l] and LiAsPha [2, 31 stereospecifically to form the corresponding vinylic diphosphines and diarsines in high yield. However cis 1,2dichloroethylene and NaAsMea produce 1,2-bis(dimethylarsino)ethylene, MeaAsCH = CHAsMea, in approximately 30% with