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Solubility of gases in polymers


Book ID
117651201
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
177 KB
Volume
2000
Category
Article
ISSN
0958-2118

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Novel correlation for solubility of gase
โœ Y. Yampolskii; D. Wiley; C. Maher ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 183 KB ๐Ÿ‘ 2 views

Novel correlations are proposed for the solubility coefficients of gases (S) as well as the parameters of the dual mode sorption isotherms k D and b in polymers. They are based on the concept of molecular surface areas of dissolved species. Van der Waals surface areas (WSA) as estimated using UNIFAC

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โœ Giulio C. Sarti; Ferruccio Doghieri ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 218 KB

A reliable, predictive model for the solubility of gases and vapours in glassy polymers has been recently presented: it is based on the free energy expression for the polymer penetrant mixture as obtained from the lattice fluid theory and on the idea that the partial polymer density is an internal s