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Solubility of CO in the ionic liquid [bmim][PF6]

✍ Scribed by Jacek Kumełan; Álvaro Pérez-Salado Kamps; Dirk Tuma; Gerd Maurer


Book ID
108131941
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
85 KB
Volume
228-229
Category
Article
ISSN
0378-3812

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Oxidation of aromatic aldehydes in the i
✍ Joshua Howarth 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 79 KB

Several aromatic aldehydes have been oxidised using the catalyst [Ni(acac) 2 ] and dioxygen at atmospheric pressure, as the oxidant, in the ionic liquid [bmim]PF 6 . The catalyst and ionic liquid could be recycled after extraction of the carboxylic acid product.

The coupling of aryl halides in the ioni
✍ Joshua Howarth; Paraic James; Jifeng Dai 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 55 KB

Several aryl halides have been coupled using the zero valent nickel catalyst [(PPh 3 ) n Ni(0)], to give the biaryl in moderate to good yield, employing the ionic liquid [bmim]PF 6 . The ionic liquid and catalyst were recycled after extraction of the biaryl.