Solubility in water of triblock (PEP) copolymers of ethylene and propylene oxides
✍ Scribed by Lubomír Šimek; Stanislav Petřík; František Hadobaš; Miloslav Bohdanecký
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 231 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
A~traet--Aqueous solutions of hydroxyl-terminated triblock copolymers of ethylene and propylene oxides display turbidity, both on heating and cooling. The lower critical solution temperatures increase with increase in the content of ethylene oxide units. Phase diagrams obtained with acetyl-terminated copolymers are more involved and give evidence of an important effect of end groups.
📜 SIMILAR VOLUMES
Specific volumes of aqueous solutions of triblock (PEP) copolymers of ethylene oxide and propylene oxide at solute weight fractions 0.1 Q w2 Q 0.39 were measured in the temperature range from 5 to 65°C. Partial molar volumes r2 per chain repeat unit, their temperature quotient 8r2,1aT, and excess pa
Suzuki reaction under phase transfer conditions: 15 mmol phenylboronic acid, 13 mmol p-iodoanisole, 0.01 mmol PdCl 2 [Ph 2 P(CH 2 ) 4 SO 3 K] 2 , 45 mmol Na 2 CO 3 in toluene/ethanol/water = 15 : 15 : 15 ml with 400 mg of different block copolymers; at 78 8C
Measurements have been made to determine the solubilities of three hydrocarbon gases, methane, ethane, and propane, in aqueous solutions of four different water-soluble triblock copolymers of the Pluronic class: Pluronic P103, P104, P105, and F108. The solubilities of each gas, measured at 25 • C, f