Solubility and mobility of aromatic hydrocarbons in pyridine
β Scribed by J. M. H. Fortuin; H. N. M. Dormans; D. W. van Krevelen
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 270 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0165-0513
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β¦ Synopsis
Abstract
The solubilities of some aromatic hydrocarbons in pyridine have been measured. The entropies of fusion derived from these measurements agree qualitatively with the values which can be calculated, if it is assumed that their molecules obtain one rotational and three translational degrees of freedom when melting occurs.
π SIMILAR VOLUMES
The recent report (1) that derivatives of 2,5,6-trifluoro-3,4-pyridyne could not bs obtained by the decomposition of 2,3,5,6-tetrafluoro~pyridyl-lithium in the presence of fursn and other aryne traps prompts us to publish the results of our experiments on related chloro-compounds.