Solubilities of chromium(III) in molten potassium hydrogensulfate
β Scribed by L. Durand-Keklikian; J. Vedel
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 319 KB
- Volume
- 192
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
The behavior of chromium(II1) in molten potassium hydrogensulfate (220" C, P(H,O) = 0.04 atm) is reported. Chromium(II1) exists as Cr" in acidic medium, and as chromium(II1) sulfate, which is insoluble in neutral medium but soluble in basic medium as Cr(S0,);. The values of acidity constants and the solubilities of Cr(II1) are reported.
π SIMILAR VOLUMES
## Abstract Perturbedβhardβchain theory is extended to mixtures of polymers and volatile fluids, including supercritical gases. This extension is used to derive an expression for Henry's constant for a solute in a molten polymer. Theoretical calculations and data reduction are reported for a variet
The title compound, transΒ±K[Cr(C 3 H 2 O 4 ) 2 (H 2 O) 2 ]Γ3H 2 O, comprises an octahedral coordinated Cr atom, bonded to two malonato ions and two water molecules and a K ion surrounded by nine O atoms.