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Solid-state structures and superstructures of two charged donor–acceptor rotaxanes

✍ Scribed by Yan-Li Zhao; Alexander K. Shveyd; J. Fraser Stoddart


Book ID
104098411
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
738 KB
Volume
52
Category
Article
ISSN
0040-4039

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The process of intramolecular charge separation was studied in three nearly identical donor-bridge-acceptor compounds (1-3) under jet-cooled conditions. Each consists of a vinylcyanonaphthalene group as a powerful electron acceptor and an anilino derivative as an electron donor, separated by a rigid