Solid-State Structure, Organization and Properties of Peptide-Synthetic Hybrid Block Copolymers
✍ Scribed by Harm-Anton Klok; Sebastien Lecommandoux
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Peptide β‐hairpin formation is facilitated by centrally positioned D‐Pro‐Xxx segments. The synthetic peptides Boc‐Leu‐Phe‐Val‐D‐Pro‐Ac~6~c‐Leu‐Phe‐Val‐OMe (**1**) and Boc‐Leu‐Phe‐Val‐D‐Pro‐Ac~8~c‐Leu‐Phe‐Val‐OMe (**2**) were synthesized in order to explore the role of bulky 1‐aminocyclo
## Abstract The cover picture shows the three‐dimensional supramolecular arrangement of 1,10‐phenanthroline (phen) residues in compound (Hphen)~6~[Ge~6~(OH)~6~(hedp)~6~]·2(phen)·20H~2~O (where H~4~hedp stands for etidronic acid). Protonated organic residues, Hphen^+^, π‐π‐stack along the [101] dire