Solid-State Structure and Mechanical Properties of Blends of an Amorphous Polyamide and a Poly(amino-ether) Resin

✍ Scribed by Ainhoa Granado; José I. Eguiazábal; Jon Nazábal

• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 257 KB
• Volume: 289
• Category: Article
• ISSN: 1438-7492
• DOI: 10.1002/mame.200300223

✦ Synopsis

Abstract

Summary: Finely dispersed blends of an amorphous polyamide (AP) and a poly(amino‐ether) (PAE) resin were obtained by direct injection moulding. The blend components reacted slightly, mainly in PAE‐rich compositions, as seen by torque increases and FT‐IR. Both negative volumes of mixing and preferential orientation were observed in blends with very high AP contents, leading to synergisms in both the modulus of elasticity and the yield stress. In PAE‐rich blends, the effects of these two structural characteristics were negative, but the higher presence of reacted products also led to an overall synergistic modulus of elasticity. With the exception of blends very rich in PAE, in which the more extensive reactions led to brittle materials, the reactions compatibilized the blends due to the presence of small amounts of reacted copolymers, probably at the interface.

Cryogenically fractured surface of the skin of the AP/PAE 80/20 w/w blend.

imageCryogenically fractured surface of the skin of the AP/PAE 80/20 w/w blend.