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Solid-State Structural and Magnetic Investigations of {M[HC(3,5-Me 2 pz) 3 ] 2 }(BF 4 ) 2 (M = Fe, Co, Ni, Cu): Observation of a Thermally Induced Solid-State Phase Change Controlling an Iron(II) Spin-State Crossover

✍ Scribed by Reger, Daniel L.; Little, Christine A.; Smith, Mark D.; Long, Gary J.


Book ID
127363038
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
136 KB
Volume
41
Category
Article
ISSN
0020-1669

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Synthesis, solid-state structure, magnet
✍ Daniel L. Reger*; Christine A. Little; Arnold L. Rheingold; Roger Sommer; Gary J 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 133 KB

The reaction of Fe(BF 4 ) 2 •6H 2 O and one equivalent of HC(3,5-Me 2 pz) 3 in acetonitrile leads to the formation of {Fe[HC(3,5-Me 2 pz) 3 ](H 2 O) 3 }(BF 4 ) 2 . The solution phase 1 H NMR spectrum is broad with chemical shifts ranging from 54 to -42 ppm, a range that is indicative of a paramagnet