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Solid-state polymerization of poly(ethylene terephthalate)

✍ Scribed by Shuya Chang; Ming-Fa Sheu; Shu-May Chen


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
615 KB
Volume
28
Category
Article
ISSN
0021-8995

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A mathematical model for solid-state polymerization of poly(ethylene terephthalate) was developed. The effects of temperature and chain entanglement on chain mobility were considered to estimate the rate constants of chemical reactions. The diffusivities of volatile byproducts could be determined us

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## Abstract A simple kinetic model capable of describing the behaviors of solid‐state polymerization (SSP) of poly(ethylene terephthalate) (PET) has been developed. According to this model, there are two types of end groups, namely active end groups and inactive end groups, and the solid‐state poly