Solid-state polymerization of derivatives of 2,4,6-octatriyne: 9. Topochemical reactions of monomers with conjugated triple bonds

Solid-State Reactions of AgAc with TabHP

Solid-State Reactions of AgAc with TabHPF6 at Room Temperature − Isolation and Structural Characterisation of an Unusual Octadecanuclear Silver Thiolate Cluster [Ag9(Tab)8(MeCN)8]2(PF6)18·4MeCN [Tab = 4-(trimethylammonio)benzenethiolate]

✍ Jin-Xiang Chen; Qing-Feng Xu; Ying Xu; Yong Zhang; Zhong-Ning Chen; Jian-Ping La 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB

## Abstract The room‐temperature solid‐state reaction of silver acetate with TabHPF~6~ [Tab = 4‐(trimethylammonio)benzenethiolate] followed by recrystallization from MeCN afforded a unique octadecanuclear silver thiolate complex [Ag~9~(Tab)~8~(MeCN)~8~]~2~(PF~6~)~18~·4MeCN (1). An X‐ray analysis of