𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Solid state polymeric electrolytes based on poly(epichlorohydrin)

✍ Scribed by G.Goulart Silva; N.H.T. Lemes; C.N.Polo da Fonseca; M.-A. De Paoli

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
929 KB
Volume
93
Category
Article
ISSN
0167-2738

No coin nor oath required. For personal study only.

✦ Synopsis

Elastomers constituted of the homopolymer of epichlorohydrin, its copolymer with ethylene oxide and its terpolymer with ethylene oxide and allyl-glycidyl-ether were studied as polymeric electrolytes in polymer/LiClO, systems. The variation of the ionic conductivity with salt concentration indicated that the copolymer and the terpolymer show the highest conductivities, ca. IO-' S cm-' at 30Β°C. Also, the fitting of the ionic conductivity versus inverse of temperature curves with the VTF equation indicated a conductivity mechanism similar to poly(ethylene oxide) for the copolymer and the terpolymer. The potential stability window determined by cyclic voltammetry is 3.5 V and the polymers are stable to heating up to 250Β°C. These results confirm the feasibility of using the copolymer and the terpolymer systems with LiClO, as polymeric solid state electrolytes.

πŸ“œ SIMILAR VOLUMES

Single-ion conducting polymeric electrol
Single-ion conducting polymeric electrolytes based on sulfonated poly(phenylene oxide)
✍ Chuanqing Wang; Yuhui Huang; Guangmin Cong; Guo Lin; Shulu Zhao πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 211 KB

In the present paper, the ionic conducting properties of sulfonated poly(phenylene oxide) (PPO) and its alkali-metal salts were investigated in detail. It was found that the material had moderate conductivity, which could reach as high as 10 06 S/cm at room temperature. Its conductivity dependence o

Solid electrolytes based on poly(amide 6
Solid electrolytes based on poly(amide 6-b-ethylene oxide)
✍ R.A. Zoppi; C.M.N.P. Fonseca; Marco-A. De Paoli; S.P. Nunes πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 710 KB

An amide 6-b-ethylene oxide copolymer (PebaxB) was investigated as an ionic conducting matrix. Transparent and flexible films containing LiClO, were prepared with ionic conductivities in the range of 10m6 S cm-' at room temperature. The conductivity values gradually increased when the films were hea