Solid State Optical Activity of Dichalcogenides: Isolation by Chiral Crystallization and Determination of Absolute Configuration
β Scribed by Shimizu, Toshio; Isono, Hiromi; Yasui, Masanori; Iwasaki, Fujiko; Kamigata, Nobumasa
- Book ID
- 126334493
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 69 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
Abba%act Enantiomeric purities and absolute configurations of chiral 8-propiolactones can be easily determined from the NMR spectra of diastereomeric solvates resulting from the interaction between the lactone and optically active 2,2,2 trifluoro-1 (9-anthryl) ethanol. Chiral 8-propiolactones subst
## Abstract Both enantiomers of an optically active trialkynyl(phenyl)methane (the key building blocks in the construction of a stable expanded cubane) have been prepared. The strategy involved the resolution of a racemic intermediate by means of HPLC on a chiral stationary phase. The absolute conf