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Solid-state NMR studies on the mechanism of the opsin shift in the visual pigment rhodopsin

✍ Scribed by Smith, Steven O.; Palings, Ilona; Miley, Mary E.; Courtin, Jacques; De Groot, Huub; Lugtenburg, Johan; Mathies, Richard A.; Griffin, Robert G.


Book ID
127009973
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
926 KB
Volume
29
Category
Article
ISSN
0006-2960

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The opsin shift and mechanism of spectra
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## Abstract Molecular dynamics simulations and combined quantum mechanical and molecular mechanical calculations have been performed to investigate the mechanism of the opsin shift and spectral tuning in rhodopsin. A red shift of βˆ’980 cm^βˆ’1^ was estimated in the transfer of the chromophore from met