✦ LIBER ✦

Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

✍ Scribed by Melinda J. Duer; Muhammad S. Khan; Ashok K. Kakkar

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 325 KB
Volume: 1
Category: Article
ISSN: 0926-2040
DOI: 10.1016/0926-2040(92)90005-t

No coin nor oath required. For personal study only.

✦ Synopsis

Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric sigma-acetylide complexes of platinum, trans-[ClPt(PnBu3)2-C identical to C-p-C6H4-C identical to C-Pt(PnBu3)2Cl] and trans-[-Pt(PnBu3)2-C identical to C-p-C6H4-C identical to C-]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

📜 SIMILAR VOLUMES

Electron transfer in trans-[Pt(PPh3)2(-C

Electron transfer in trans-[Pt(PPh3)2(-CCFc)2] and related compounds

✍ Domenico Osella; Olimpia Gambino; Carlo Nervi; Mauro Ravera; Maria Vittoria Russ 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 470 KB

Novel secondary allenylidene ruthenium c

Novel secondary allenylidene ruthenium complexes and preparation of trans-[(dppm)2(H)RuCCCH(OMe)R] derivatives

✍ Nadine Pirio; Daniel Touchard; Pierre H. Dixneuf 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 220 KB

Laser induced excitation spectra of the

Laser induced excitation spectra of the cations of 1,3-pentadiynes, R(CC)2H+; R  CH3, CD3: (A2E ← X2E) and of 2,4-hexadiynes, R (CC)2R+; R  CH3, CD3; (A2Eu ← X2Eg) in the gaseous phase

✍ John P. Maier; Liubomir Misev 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 637 KB

Electrochemical studies on organometalli

Electrochemical studies on organometallic compounds: XLII. Electrogeneration and spectroscopic characterization of [Nb(η-C5H4SiMe3)2(PhC  CPhC,C)]

✍ H. Chollet; D. Lucas; Y. Mugnier; A. Antiñolo; A. Otero; M. Fajardo 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 250 KB

Intramolecular addition of monomeric ary

Intramolecular addition of monomeric arylcopper entities across an alkyne grouping in a complex of type [(η5-C5H4SiMe3)2 Ti(CCSiMe3)2]CuR; X-ray structure of [(η5-C5H4SiMe3)2Ti(CCSiMe3) μ-CC(SiMe3)(C6H3(CH2NMe2)2-2,6) Cu

✍ Maurits D. Janssen; Wilberth J.J. Smeets; Anthony L. Spek; David M. Grove; Heinr 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 363 KB

Thermal decomposition of (η)-cyclopentad

Thermal decomposition of (η)-cyclopentadienyl)- tricarbonyl(σ-phenylethynyl)molybdenum and the molecular structure of a molybdenum binuclear complex with a bridging 1,4-diphenylbutadiyne ligand [η- C5H5)(CO)2Mo]2(μ-1,2-η-C6H5CCCCC6H5)

✍ N.A. Ustynyuk; V.N. Vinogradova; V.N. Korneva; D.N. Kravtsov; V.G. Andrianov; Yu 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 719 KB