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Solid-state high-resolution 29Si mas MAR of silicates with sixfold coordinated silicon

✍ Scribed by A.-R. Grimmer; F. von Lampe; M. Mägi

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 376 KB
Volume: 132
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)87122-6

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✦ Synopsis

A correlation between isotropic ?Si chemical shifts and mean Si-0 bond length is presented for ten silicates containing sixfold coordinated silicon. The %i chemical shift data afford a measure of the cationic, neutral or anionic character of the octahedral silicon.

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