Solid-state 119Sn NMR studies of coordination in triorganyltin fluorides
✍ Scribed by Haiping Bai; Robin K. Harris; Hans Reuter
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 359 KB
- Volume
- 408
- Category
- Article
- ISSN
- 0022-328X
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## Abstract ^119^Sn NMR data are reported for organotin compounds containing potentially C,N‐chelating ligands capable of forming five‐ or six‐membered chelate rings. The ^119^Sn chemical shifts of divalent organotin compounds containing such a ligand are found at relatively high frequency. Intramo
The 119Sn magic angle spinning NMR spectra of the three tin sulÐdes SnS, and are discussed with SnS 2 Sn 2 S 3 respect to results from x-ray structure analysis. The distortion from an octahedral environment of tin in SnS and Sn(II) in is reÑected in the large chemical shift anisotropy. The denser co
## Abstract Extremely broad ^119^Sn resonances, as the result of ^1^__J__(^119^Sn,^11^B) scalar coupling, were readily detected, even for diluted samples (5 mg in 0.5 ml of C~6~D~6~), via inverse two‐dimensional ^1^H{^119^Sn} NMR experiments. Two bis(amino)trimethylstannylboranes and four dialkylam