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Solid-Phase Synthesis of Tetrahydro-β-carbolines and Tetrahydroisoquinolines by Stereoselective Intramolecular N-Carbamyliminium Pictet–Spengler Reactions

✍ Scribed by Frederik Diness; Jürgen Beyer; Morten Meldal

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
29 KB
Volume
13
Category
Article
ISSN
0947-6539

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Enantiospecific Formation of trans-1,3-Disubstituted Tetrahydro-βcarbolines by the Pictet-Spengler Reaction and Conversion of cis Diastereomers into Their trans Counterparts by Scission of the C-1/N-2 Bond. -The factors which effect the stereoselective formation of trans-products in the Pictet-Spen