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Solid-phase synthesis of natural product-like macrocycles by a sequence of Ugi-4CR and SNAr-based cycloetherification

✍ Scribed by Pierre Cristau; Jean-Pierre Vors; Jieping Zhu

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 221 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01378-9

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✦ Synopsis

An on-resin Ugi four-component reaction followed by an intramolecular nucleophilic aromatic substitution (S N Ar) has been developed for the rapid access to biaryl-ether containing macrocycles.

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