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Solid-phase synthesis and characterization of rare-earth chromates

✍ Scribed by E. V. Leutkina; N. A. Puretskii; A. P. Bobylev; L. N. Komissarova

Book ID
110188085
Publisher
Springer
Year
2007
Tongue
English
Weight
130 KB
Volume
41
Category
Article
ISSN
0040-5795

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The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual Β΅ 2 ,Ξ· 4 :Ξ· 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc