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Solid-Phase Immobilization of a New Epoxidation Catalyst

✍ Scribed by Simon Krijnen; Hendrikus C. L. Abbenhuis; Rob W. J. M. Hanssen; Jan H. C. van Hooff; Rutger A. van Santen

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 97 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980216)37:3<356::aid-anie356>3.0.co;2-5

No coin nor oath required. For personal study only.

✦ Synopsis

The heterogenization of a titanium(IV) silsesquioxane complex in an MCM-41 molecular sieve, by tailoring the polarity of MCM-41, results in self-assembled materials (see the space-filling model on the right) that are active, truly heterogeneous, and recyclable catalysts for liquid-phase alkene epoxidation.

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