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Solid-Phase Extraction of Phenol and Chlorophenols in Water with a Chemically Modified Polymer-Supported Tetrakis(p-carboxyphenyl) Porphyrin (H2TCPP)

✍ Scribed by Do-Gyun Kim; Min-Woo Jung; Insook Rhee Paeng; Jae-Seong Rhee; Ki-Jung Paeng


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
42 KB
Volume
63
Category
Article
ISSN
0026-265X

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✦ Synopsis


A chemically modified sorbent was evaluated as a preconcentration substrate in solid-phase extraction of phenol and chlorophenols. Tetrakis(p-carboxyphenyl) porphyrin (H 2 TCPP) was chemically bonded to porous polymeric XAD resins by ketone linkage. Breakthrough volumes, recovery values, and detection limits were determined. The synthesized sorbent showed higher recoveries in tap water than commercially available sorbents such as XAD-2 and XAD-4.