Solid Phase Diels−Alder Reactions of Amino Acid Derived Trienes
✍ Scribed by Sun, Sengen; Murray, William V.
- Book ID
- 127031388
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 98 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0022-3263
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191 a) Dr. A. Meyer, Stuttgart is thanked for the elemental analyses; b) Gd5CIVC2 is monoclinic, space group P2,/c (No. 14), a=918.2(3), b=1612.0(5), C = 1288.6(4) pm,/3= 119.86(2)"; Z = 4 ; R=0.026 with 3539 reflexions I > 2 a (I).
## Abstract Derivatives 7–10 and 13–16 of methyl and ethyl 2‐azabicyclo[2.2.1]heptane‐3‐carboxylates are synthesized by Aza‐Diels‐Alder reactions of chiral iminium ions, formed in situ from glyoxylic acid and chiral amines, with cyclopentadiene. Whereas the heterodienophiles derived from phenylglyc