Sol−Gel Materials for Second-Order Nonlinear Optics
✍ Scribed by Chaumel, Frederic; Jiang, Hongwei; Kakkar, Ashok
- Book ID
- 120732390
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 97 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0897-4756
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A series of the organically modified inorganic NLO sol-gel materials based on the prepolymer of alkoxysilanes and an alkoxysilane dye (ASD) have been investigated. Optically clear samples exhibit large second-order optical nonlinearity (d 33 ϭ ϳ10.8 -54.0 pm/V at 1064 nm) after poling and curing at
A series of all organic nonlinear optical (NLO) sol-gel materials based on melamines and an azobenzene dye (Disperse Orange 3; DO3) have been investigated. Different contents of DO3 were covalently bonded with the melamine-based organic network via condensation of amino and methylol groups. The opti