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Solasodine and diosgenin: 1H and 13C assignments by two-dimensional NMR spectroscopy

✍ Scribed by Raman Puri; Tuck C. Wong; Ravi K. Puri

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 393 KB
Volume: 31
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260310313

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✦ Synopsis

Abstract

Solasodine and diosgenin have been widely used as starting materials for the partial synthesis of cortisone, progresterone and C21 steroidal derivatives (oral contraceptives). This study involved the total ^1^H and ^13^C spectral assignments of these two important compounds by using two‐dimensional NMR techniques (COSY, CSCM and HMBC), and resulted in unambiguous spectral assignments, especially in the convoluted regions of the spectra (^1^H, 0.7–2.0 ppm; ^13^C, 28–35 ppm).

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