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Soil sorption of organic vapors and effects of humidity on sorptive mechanism and capacity

โœ Scribed by Chiou, Cary T.; Shoup, Thomas D.

Book ID
126304987
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
659 KB
Volume
19
Category
Article
ISSN
0013-936X

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During supposedly isothermal sorption/desorption of gases or vapors by solid polymers, latent heat effects alter local temperatures with the result that diffusion behavior may appear to be non-Fickian. Even when sorption curves are seemingly Fickian, spurious values of the diffusion coefficient, D,