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Soil persistence and metabolism of N-sec-butyl-4-tert-butyl-2,6-dinitroaniline

✍ Scribed by Kearney, Philip C.; Plimmer, Jack R.; Williams, Virginia P.; Klingebiel, Ute I.; Isensee, Allan R.; Laanio, Tapio L.; Stolzenberg, Gary E.; Zaylskie, Richard G.


Book ID
126899875
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
483 KB
Volume
22
Category
Article
ISSN
0021-8561

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trrf-Butyl and 2,6-di(tert-butyl)-4-methylphenyl (RHT) cyclopropanecarboxylates (4, 6, 24, 25) are lithiated with LiN(i-Pr), and t -BuLi, respectively. Reactions with alkyl halides, aldehydes, acyl chlorides, and heteroelectrophiles give a-substituted BHT esters which can be cleaved (t-BuOK/H,O/THF)